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Gandour, Kevin J. Remarkably regioselective deacylation of cellulose esters using tetraalkylammonium salts of the strongly basic hydroxide ion.
European Journal of Organic Chemistry , 17 , Pires, Antonio C. Borin, Omar A. Industrial Crops and Products , 54 , Allen, Thomas T.
Structure and Mechanism in Ketene Chemistry. Pires, Omar A. Acylation of cellulose in a novel solvent system: Solution of dibenzyldimethylammonium fluoride in DMSO.
Regioselective acetylation of carbohydrates and diols catalyzed by tetramethyl-ammonium hydroxide in water. Green Chem. TBAF-catalyzed deacylation of cellulose esters: Reaction scope and influence of reaction parameters.
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Many applications tolerate heterogeneous or ill-defined fluoride sources. As a fluoride source in organic solvents, TBAF is used to remove silyl ether protecting groups.
It is also used as a phase transfer catalyst and as a mild base. As a deprotecting agent, TBAF in DMSO will convert O-silylated enolates into carbonyls.
With C-Si bonds, TBAF gives carbanions that can be trapped with electrophiles or undergo protonolysis. From Wikipedia, the free encyclopedia. Tetra- n -butylammonium fluoride Names IUPAC name Tetra- n -butylammonium fluoride.
Tetrabutylammonium fluoride; TBAF; n -Bu 4 NF. CAS Number. A mixture of the SM mg, 0. Upon completion, the resulting solution was. Reagent in substitution reactions with TMSCN.
A solution of the SM
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A solution of the SM CsF or KF Cookie Spiele Kostenlos
NH4F may do the deprotection job as well as TBAF while they will not mess up in your column. Other names Tetrabutylammonium fluoride; TBAF; Formel 1 Meiste Siege
-Bu 4 NF. Your Mendeley pairing has expired. FCC did not work at all. PubChem CID. The good solubility of TBAF in organic solvents makes it a useful alternative to poorly soluble inorganic bases. Please note: N26 GeschГ¤ftskonto Erfahrungen
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